Ammonium dodecylbenzene sulphonate
Time: 2012-09-28 16:25:00

Ammonium dodecylbenzene sulphonate

Synonyms

Benzenesulfonic acid, dodecyl-, ammonium;

Dodecyl benzenesulfonic acid ammonium salt;

Dodecylbenzenesulfonic acid, ammonium salt;

Benzenesulfonic acid, dodecyl-, ammonium salt;

Dodecylphenyl ammonium sulfonate;

Ammonium lauryl benzene sulfonate;

Ammonium dodecylbenzene sulfonate;

Category

Anionic Surfactant

> Sulfonate

>> Aryl Sulfonate

>>> Phenyl Sulfonate

>>>> Linear Alkylphenyl Sulfonate

Chemical Numbering System

CASRN1331-61-9

EINECS215-559-8

Molecular Formula & Molecular Weight

Molecular Formula: C18H33NO3S;C18H30O3S.H3N

Molecular Weight: 343.52

Structure

Properties

Appearance    (1), colorless to pale yellow liquid; (2), solid.

Solubility    soluble in water.

Stability    unstable in alkali, release ammonia.

Risk    Solid form: flammable material; irritation, moderate irritation to skin, eye, respiratory. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.

GHS (Rev.7) label:  

Liquid form: irritation, moderate irritation to skin, eye.

GHS (Rev.7) label: 

Ecology    may be hazardous to environment. Water body should be given special attention.

Biodegradability    biodegradable.

Characteristics    excellent cleansing, foaming, emulsifying, wetting, dispersing, solubilizing abilities. Weak resistance to hard water, used in conjunction with chelating agent. Good compatibility. Under sodium chloride, non-foaming or low foaming.

Note    (1), Avoid using in children cleaning products, such as shower gels, shampoo.

Synthesis

Currently, sulfonation reaction through continuous reactor (such as: falling film reactor) is the most widely used method for preparing sulfonates.

Generally, dodecylbenzene and sulfur trioxide react through reactor, then ammonia water neutralizes, finally obtain product.

US patent 8,921,588 (Process for preparing sulfates and/or sulfonates in a micro-reaction system) presents a synthetic process. Conditions: mole ratio of sulfur trioxide and alkyl benzenes or other raw materials: 1:1; temperature: 30-60°C; reactor: falling film reactor.

Quality Standards & Test Methods

1, Physical and chemical indexes

Item

Physical and chemical indexes

Liquid

Actives, %, ≥

30.0 - 50.0

pH (25°C, 1%)

4.5 - 7.0

Test Methods

(1), Actives

GB/T 5173 Surface active agents and detergents-Determination of anionic-active matter by direct two-phase titration procedure

ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure

(2), pH

GB/T 6368 Surface active agents - Determination of pH of aqueous solution - Potentiometric method

ISO 4316 Surface active agents -- Determination of pH of aqueous solutions -- Potentiometric method

2, Hazardous substances indexes

Item

Hazardous substances indexes

Liquid

Solid

Heavy metals (as Pb), mg/Kg, ≤

20

20

As, mg/Kg, ≤

3

3

Test Methods

(1), Heavy metals (as Pb)

Safety and Technical Standards for Cosmetics (2015 Edition)

GB/T 30799 The test method of food detergents - Determination of heavy metals

(2), As

Safety and Technical Standards for Cosmetics (2015 Edition)

GB/T 30797 The test method of food detergents - Determination of total arsenic

3, Further explanation

(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.

(b), Used in cosmetics, should be test for harmful substances; or furtherly test for microorganisms.

Major Uses

1, Typical applications

Use as cleansing agent.

Use as emulsifying agent, dispersing agent.

2, Household detergents

Use as cleansing agent, foaming agent.

3, Industrial cleaning agents

Use as cleansing agent.

4, Emulsion polymerization

Emulsifier, particle size controlling agent in emulsion polymerization.

5, Personal care products

Use as cleansing agent, foaming agent.

6, Petroleum

Oil recovery agent in petroleum.

Foaming agent, suspending agent in drilling fluids.

7, Pets

Use as cleansing agent, foaming agent.

Manufacturers

 

Update: 20131025(1); 20170310(2);