Petroleum Sulfonic Acid, Barium Salt
Time: 2012-09-29 16:40:06
Petroleum Sulfonic Acid, Barium Salt
Synonyms
Sulfonated petroleum, barium salt;
Sulfonic acids, petroleum, barium salts;
Barium petroleum sulfonate;
T701;
Category
Anionic Surfactant
>> Sulfonate
>> Aryl Sulfonate
>> Natural Substance Sulfonate
>> Natural Substance (Petroleum Source) Sulfonate
Chemical Numbering System
CASRN61790-48-5
EINECS263-140-3
Molecular Formula & Molecular Weight
Molecular Formula: N/A
Molecular Weight: N/A
Structure
 
Properties
Appearance    (1), brown semi-solid or flowing liquid; (2), solid.
Solubility    insoluble in water.
Stability    stable.
Risk    Solid form: flammable material; irritation, moderate irritation to skin, eye, respiratory. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.
GHS (Rev.6) label:  
Liquid form: flammable material; irritation, moderate irritation to skin, eye. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.
GHS (Rev.6) label:  
Ecology    may be hazardous to environment. Water body should be given special attention.
Biodegradability    biodegradable.
Characteristics    excellent antirust, anticorrosive, lubricating, emulsifying, solubilizing, dispersing abilities. Good anti-rust effect to ferrous metals. To acid medium, has a good neutralization and replacement abilities. Flow-type product has a good oil solubility, and it is easy to use.
Synthesis
Currently, sulfonation reaction through continuous reactor (such as: falling film reactor) is the most widely used method for preparing sulfonates.
Generally, distillate oil (Typical: lubricating oil distillate) and sulfur trioxide react through reactor, then barium hydroxide neutralizes, finally obtain product.
US patent 8,921,588 (Process for preparing sulfates and/or sulfonates in a micro-reaction system) presents a synthetic process.
Quality Standards & Test Methods
1. Physical and chemical indexes
Item
Physical and chemical indexes
Actives, %, ≥
40.0 - 60.0
Test Methods
(1), Actives
GB/T 5173 Surface active agents and detergents-Determination of anionic-active matter by direct two-phase titration procedure
ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure
2. Product standards
(1), Chinese standards
(1a), SH/T 0391 Rust inhibitor 701 (oil soluble barium petroleum sulfonate)
3. Further explanation
(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.
Major Uses
1. Typical applications
Use as rust inhibitor, anticorrosive agent.
Use as lubricant.
2. Lubrication
Use as lubricant.
3. Rust protection, corrosion inhibition
Use as rust inhibitor widely. Such as replacement anti-rust oil, archive antirust oil, lubricating anti-rust oil, antirust grease and so on.
Manufacturers
 
Update: 20131025(1); 20170405(2);