MEA-laureth carboxylate
Synonyms
Poly(oxy-1,2-ethanediyl), alpha-carboxymethyl-omega-dodecyloxy-, 2-aminoethanol salts;
PEG Lauryl ether carboxylic acid, 2-aminoethanol salt;
Category
Anionic Surfactant
> Carboxylate
>> Polyether Carboxylate
>>> Alkyl Polyether Carboxylate
>>>> Linear Alkyl Polyoxyethylene Ether Carboxylate
Chemical Numbering System
CASRN:N/A
EINECS:N/A
Molecular Formula & Molecular Weight
Molecular Formula: (C2H4O)nC14H28O3.C2H7N1O
Molecular Weight: N/A
Structure
Properties
Appearance (1), liquid; or solid.
Solubility soluble in water.
Stability stable. Stable to acid, alkali, hard water.
Risk Liquid form: irritation, low irritation to skin, eye.
GHS (Rev.10) label:
Ecology may be hazardous to environment. Water body should be given special attention.
Biodegradability biodegradable.
Characteristics excellent cleansing, emulsifying, dispersing, foaming, foam stabilizing, wetting, solubilizing abilities. Resistance to high concentrations of alkali. Resistance to oxidants. Resistance to high temperature. Good compatibility. Can be compounded with cationic surfactants without affecting each other. Mild surfactant. Can reduce irritation of other surfactants. Under acidic condition, do not affect cleansing, foaming effects. Performance varies with EO number.
Note (1), 1,4-dioxane generated during polyether preparation: probable carcinogen. However, can be acceptable when concentration of 1,4-dioxane is less than 30ppm or less.
(2), Should not be used in children products that can be direct prolonged contact with the skin, such as skin care products.
(3), Avoid using in children cleaning products, such as shampoos.
(4), Do not use in nitrosating environment. Reaction of monoethanolamine and nitrous acid can not produce nitrosamines, however, reaction of contained secondary amine of monoethanolamine and nitrous acid can produce nitrosamines. Nitrosamine is a carcinogen.
Synthesis
Quality Standards & Test Methods
1, Physical and chemical indexes
Item |
Physical and chemical indexes |
Liquid |
|
Actives, %, ≥ |
30.0 |
Chloroacetic acid*, ppm, ≤ |
10 |
*: Only applicable to products using chloroacetic acid process. |
Test Methods
(1), Actives
GB/T 13173 Surface active agents - Detergents - Testing methods
GB/T 5173 Surface active agents and detergents-Determination of anionic-active matter by direct two-phase titration procedure
ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure
(2), Chloroacetic acid
QB/T 2950 Alkylpolyethoxy Carboxylate
2, Hazardous substances indexes
Item |
Hazardous substances indexes |
Liquid |
|
Heavy metals (as Pb), mg/Kg, ≤ |
20 |
As, mg/Kg, ≤ |
3 |
Test Methods
(1), Heavy metals (as Pb)
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30799 The test method of food detergents - Determination of heavy metals
(2), As
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30797 The test method of food detergents - Determination of total arsenic
3, Further explanation
(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.
(b), Used in cosmetics, should be test for harmful substances or furtherly test for microorganisms, according to local regulations and standards.
Major Uses
1, Typical applications
Use as cleansing agent.
Use as emulsifying agent, dispersing agent.
Use as solubilizing agent.
Use as foaming agent, foam stabilizing agent.
2, Personal care products
Cleansing agent, emulsifying agent in personal care products.
* * * * * *
Further information:
(1), In accordance with EU regulations (EC) No 1223/2009, directive 2003/83/EC, monoethanolamine and its salts are included in Annex III/61.
Maximum concentration of secondary amine is 0.5% in products.
In raw materials, maximum secondary amine content is 0.5%.
Maximum nitrosamine content is 50μg/kg.
The container is nitrite-free.
(2), In accordance with Safety and Technical Standards for Cosmetics (2015 Edition) of China, monoethanolamine and its salts are the restricted components.
In raw materials, maximum secondary amine content is 0.5%.
Maximum nitrosamine content is 50μg/kg.
The container is nitrite-free.
3, Household detergents
Cleansing agent in household cleaning products.
4, Machinery
Emulsifying agent, cleansing agent in water-based metalworking fluids.
5, Industrial cleaning
Cleansing agent in industrial cleaning. Good cleaning effect on heavy oil and wax dirt.
6, Textile, leather
Cleansing agent, degreasing agent in textile, leather.
Product members
MEA-laureth-6 carboxylate;
Manufacturers
Update: 20131111(1); 20181126(2);