Benzenesulfonic acid, oxybis-, branched lauryl derivs., potassium salts
Time: 2013-10-31 16:11:20
Benzenesulfonic acid, oxybis-, branched lauryl derivs., potassium salts
Synonyms
Benzenesulfonic acid, oxybis-, branched dodecyl derivs., potassium salts;
Category
Anionic Surfactant
>> Sulfonate
>> Aryl Sulfonate
>> Phenyl Ether Sulfonate
>> Branched Alkyl Phenyl Ether Sulfonate
Chemical Numbering System
CASRN71786-48-6
EINECSN/A
Molecular Formula & Molecular Weight
Molecular Formula: N/A
Molecular Weight: N/A
Structure
Schematic formula:
R: C12-branched.
Properties
Appearance    (1), solid; (2), liquid.
Solubility    soluble in water.
Stability    stable.
Risk    Solid form: flammable material; irritation, moderate irritation to skin, eye, respiratory. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.
GHS (Rev.6) label:  
Liquid form: irritation, moderate irritation to skin, eye.
GHS (Rev.6) label:
Ecology    may be hazardous to environment. Water body should be given special attention.
Biodegradability    to a certain extent, biodegradable.
Characteristics    excellent emulsifying, dispersing, wetting, cleansing abilities.
Synthesis
Currently, sulfonation reaction through continuous reactor (such as: falling film reactor) is the most widely used method for preparing sulfonates.
Generally, branched dodecyl diphenyl ether and fuming sulfuric acid or sulfur trioxide react through reactor, then sodium hydroxide or sodium carbonate neutralizes, finally obtain product.
Refer to: US patent 8,921,588 Process for preparing sulfates and/or sulfonates in a micro-reaction system.
Quality Standards & Test Methods
1. Physical and chemical indexes
Item
Physical and chemical indexes
Solid
Actives, %, ≥
90.0
pH (25°C, 1%)
7.0 - 10.5
Test Methods
(1), Actives
 
(2), pH
GB/T 6368 Surface active agents - Determination of pH of aqueous solution - Potentiometric method
ISO 4316 Surface active agents -- Determination of pH of aqueous solutions -- Potentiometric method
2. Hazardous substances indexes
Item
Hazardous substances indexes
Liquid
Solid
Heavy metals (as Pb), mg/Kg, ≤
20
20
As, mg/Kg, ≤
3
3
Test Methods
(1), Heavy metals (as Pb)
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30799 The test method of food detergents - Determination of heavy metals
(2), As
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30797 The test method of food detergents - Determination of total arsenic
3. Further explanation
(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.
Major Uses
1. Typical applications
Use as emulsifying agent, dispersing agent.
Use as hydrotrope.
Use as wetting agent.
Manufacturers
 
Update: 20170530(1);