(C10-C16) Alkylbenzenesulfonic acid, calcium salt
Synonyms
Calcium C10-16 alkylbenzenesulfonate;
Benzenesulfonic acid, C10-16 alkyl-, calcium salt;
Calcium C10-16 alkylbenzene sulfonate;
Calcium C10-16 alkylbenzenesulphonate;
Benzenesulfonic acid, C10-16-alkyl derivs., calcium salts;
Category
Anionic Surfactant
> Sulfonate
>> Aryl Sulfonate
>>> Phenyl Sulfonate
>>>> Linear Alkylphenyl Sulfonate
Chemical Numbering System
CASRN:68584-23-6
EINECS:271-529-4
Molecular Formula & Molecular Weight
Molecular Formula: N/A
Molecular Weight: N/A
Structure
R: C10-16.
Properties
Appearance (1), solid.
Solubility insoluble in water.
Stability stable.
Risk Solid form: flammable material; irritation, moderate irritation to skin, eye, respiratory. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.
GHS (Rev.10) label:
Ecology may be hazardous to environment. Water body should be given special attention.
Biodegradability biodegradable.
Characteristics excellent emulsifying, dispersing, solubilizing, lubricating abilities.
Synthesis
Currently, sulfonation reaction through continuous reactor (such as: falling film reactor) is the most widely used method for preparing sulfonates.
Generally, C10-16 alkylbenzene and sulfur trioxide react through reactor, then calcium oxide neutralizes, finally obtain product.
US patent 8,921,588 (Process for preparing sulfates and/or sulfonates in a micro-reaction system) presents a synthetic process. Conditions: mole ratio of sulfur trioxide and alkyl benzenes or other raw materials: 1:1; temperature: 30-60°C; reactor: falling film reactor.
Quality Standards & Test Methods
1, Physical and chemical indexes
Item |
Physical and chemical indexes |
Solid |
|
Actives, %, ≥ |
90.0 |
Test Methods
(1), Actives
GB/T 5173 Surface active agents and detergents-Determination of anionic-active matter by direct two-phase titration procedure
ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure
2, Hazardous substances indexes
Item |
Hazardous substances indexes |
Solid |
|
Heavy metals (as Pb), mg/Kg, ≤ |
20 |
As, mg/Kg, ≤ |
3 |
Test Methods
(1), Heavy metals (as Pb)
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30799 The test method of food detergents - Determination of heavy metals
(2), As
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30797 The test method of food detergents - Determination of total arsenic
3, Further explanation
(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.
Major Uses
1, Typical applications
Use as emulsifying agent, dispersing agent.
Manufacturers
Update: 20170521(1);