Benzenesulfonic acid, mono- and dialkyl derivs., magnesium salts
Time: 2013-10-31 16:16:05
Benzenesulfonic acid, mono- and dialkyl derivs., magnesium salts
Synonyms
Magnesium alkylbenzenesulfonate;
Magnesium alkylbenzene sulfonate;
Magnesium alkylbenzenesulphonate;
Benzenesulfonic acid, alkyl derivs., magnesium salts;
Category
Anionic Surfactant
>> Sulfonate
>> Aryl Sulfonate
>> Phenyl Sulfonate
>> Linear Alkylphenyl Sulfonate
Chemical Numbering System
CASRN71786-47-5
EINECSN/A
Molecular Formula & Molecular Weight
Molecular Formula: N/A
Molecular Weight: N/A
Structure
Properties
Appearance    (1), solid.
Solubility    insoluble in water to soluble in water. Solubility is associated with the length of carbon chain and substitution degree.
Stability    stable.
Risk    Solid form: flammable material; irritation, moderate irritation to skin, eye, respiratory. Harmful products of combustion are CO, CO2 and so on. Contact with strong oxidants, can cause to burn.
GHS (Rev.6) label:  
Ecology    may be hazardous to environment. Water body should be given special attention.
Biodegradability    biodegradable.
Characteristics    excellent emulsifying, dispersing, solubilizing, lubricating abilities.
Synthesis
Currently, sulfonation reaction through continuous reactor (such as: falling film reactor) is the most widely used method for preparing sulfonates.
Generally, alkylbenzene and sulfur trioxide react through reactor, then magnesium carbonate or magnesium hydroxide neutralizes, finally obtain product.
US patent 8,921,588 (Process for preparing sulfates and/or sulfonates in a micro-reaction system) presents a synthetic process. Conditions: mole ratio of sulfur trioxide and alkyl benzenes or other raw materials: 1:1; temperature: 30-60°C; reactor: falling film reactor.
Quality Standards & Test Methods
1. Physical and chemical indexes
Item
Physical and chemical indexes
Solid
Actives, %, ≥
90.0
Test Methods
(1), Actives
GB/T 5173 Surface active agents and detergents-Determination of anionic-active matter by direct two-phase titration procedure
ISO 2271 Surface active agents -- Detergents -- Determination of anionic-active matter by manual or mechanical direct two-phase titration procedure
2. Hazardous substances indexes
Item
Hazardous substances indexes
Solid
Heavy metals (as Pb), mg/Kg, ≤
20
As, mg/Kg, ≤
3
Test Methods
(1), Heavy metals (as Pb)
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30799 The test method of food detergents - Determination of heavy metals
(2), As
Safety and Technical Standards for Cosmetics (2015 Edition)
GB/T 30797 The test method of food detergents - Determination of total arsenic
3. Further explanation
(a), On physical and chemical indexes: firstly, shall be indicated carbon atom distribution; secondly, shall be indicated average molecular weight.
Major Uses
1. Typical applications
Use as emulsifying agent, dispersing agent.
Use as lubricant.
Manufacturers
 
Update: 20170521(1);